Clusters spectroscopy Clusters spectroscopy

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Metal-organic clusters

Working Members:Qiuhao Yi, Demiao Ma, Peter Blessing

(Mandy)

 

We are endevouring to study the gas-phase emission of single molecules and weakly bounded molecular clusters, via a time-of-flight mass spectrometer combined with laser-induced fluorescence system .

     

Vacuum-Ultraviolet Laser Ioniaztion Mass Spectrometer combined
with Laser-induced Fluorescence system (VUV-LIF)
   
 

Picosecond time-resolved fluorescence system  

 

 

References

[1] Wu, H. M.; Yuan, C. Q.; Zhang, H. Y.; Yang, G. H.; Cui, C. N.; Yang, M. Z.; Bian, W. S.; Fu, H. B.; Luo, Z. X.*; Yao, J. N., Ultrafast Deep-Ultraviolet Laser Ionization Mass Spectrometry Applicable to Identify Phenylenediamine Isomers. Anal. Chem. 2018, 90, 10635-10640.

[2] Wu, H.; Guo, M.; Yang, M.; Luo, Z.; Hansen, K. Selective C-C and C-N Bond Activation in Dopamine and Norepinephrine under Deep Ultraviolet Laser Irradiation. Chem. Commun. 2019, 55, 4015–4018.

[3] M. Guo;  B. Huang;  Q. Yi; Z. Luo*, Gas-phase synthesis and deposition of metal-bipyridine complex [M-bpy1-2]+(M = Ag, Cu). Phys. Chem. Chem. Phys. 2021, 23 (30), 16334-16340 

[3] M. Guo;  Q. Yi;  C. Cui;  W. Gan; Z. Luo, Gas-Phase Synthesis of Metal Olefins: Plasma-Assisted Methane Dehydrogenation and C horizontal lineC Bond Formation. J. Phys. Chem. A 2022, 126, 1123–1131.

[5] Mengdi Guo;  Baoqi Yin;  Ben Huang;  Haiming Wu; Zhixun Luo, Gas-phase synthesis of Ag-centered phenylenediamine clusters. J. Mater. Chem. C 2020, 8, 10325–10332.  Doi:10.1039/d0tc02296a..